Self‐Assembled Chiral Polymers Exhibiting Amplified Circularly Polarized Electroluminescence

Abstract Circularly polarized electroluminescence (CPEL) is highly promising in realm of 3D display and optical data storage. However, designing a groundbreaking chiral material with high comprehensive CPEL performance remains a formidable challenge. In this work, a pair of chiral polymers with self‐assembled behavior is designed by integrating a chiral BN‐moiety into polyfluorene backbone, named R‐PBN and S‐PBN , respectively. The chiral polymers show narrowband emission centered at 490 nm with full‐width half maximum (FWHM) of 29 nm and high photoluminescence quantum yield (PLQY) of 79 %. After thermal annealing treatment, the chiral polymers undergo self‐assembly, exhibiting amplified circularly polarized luminescence (CPL) with asymmetry factor (| g lum |) of up to 0.11. Moreover, the solution‐processed nondoped CP‐OLEDs based on the chiral polymers as emitting layers exhibit maximum external quantum efficiency (EQE max ) of 9.8 %, intense CPEL activities with | g EL | of up to 0.07, and small FWHM of 36 nm, simultaneously. This represents the first case of self‐assembled chiral polymers that combines high EQE, large g EL value and narrowband emission.