催化作用
析氧
钴
咪唑
纳米技术
多孔性
材料科学
表面改性
金属有机骨架
化学
组合化学
化学工程
有机化学
电化学
电极
复合材料
冶金
吸附
物理化学
工程类
作者
Zihan Li,Somboon Chaemchuen
标识
DOI:10.1002/tcr.202300142
摘要
As a class of metal-organic framework, the zeolitic-imidazole framework-67 is constructed from bridging cobalt ions and 2-methylimidazole. The high content of abundant active cobalt species, uniform structure, ultrahigh porosity, and large surface area show the potential for multiple catalytic applications, especially electrocatalytic oxygen evolution reaction (OER). The design and synthetic strategies of catalyst-based ZIF-67 that approach the maximized catalytic performance are still challenging in further development. Herein, the current progress strategy on the structural design, synthetic route, and functionalization of electrocatalysts based on ZIF-67 to boost the catalytic performance of OER is reviewed. Besides, the structurally designed catalyst from various fabricated strategies corresponding to enhancing catalytic activity is discussed. The emphasized review for understanding design and synthetic structure with catalytic performance could guide researchers in further developing catalyst-based ZIF-67 for improving the efficient electrocatalytic OER.
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