Alkoxymethyl)phosphines and their derivatives

We found a preparative method for the synthesis of the substituted (alkoxymethyl)phosphines with various structure on the basis of the reactions of (alkoxymethyl)chloromagnesiums with chlorophosphines. The compositions and structures of the compounds obtained were confirmed by the results of elemental analysis and /sup 1/H and /sup 31/P NMR spectroscopy.