光催化
材料科学
可见光谱
罗丹明B
光降解
光化学
甲基橙
催化作用
降级(电信)
作者
Saleh D. Mekky,Muhammad Sultan,Mohamed M. Elsenety,Ahmed Helal,B. A. El-Sayed
标识
DOI:10.1016/j.inoche.2021.109176
摘要
• Photocatalytic degradation of rhodamine B in the visible region using CoAl 2-x La x O 4 compound. • Investigate the impact of La content on the photophysical characteristics of CoAl 2 O 4 spinel structure. • Theoretical DFT and Molecular dynamic calculations of La-doped CoAl 2 O 4 compound . • Visible emission blue shift of cobalt aluminate nanostructures in the presence of La 3+ ions. In the present research, we focused on the study of the photocatalytic activity of nanostructured CoAl 2-x La x O 4 (x =0, 0.01, 0.03, 0.07, and 0.09) as photocatalysts synthesized by the citric sol-gel method which were used for the photocatalytic degradation of rhodamine B (RhB) under visible light. Doping of lanthanum ion, La 3+ in the cobalt aluminate matrices were characterized by XRD, XPS, FT-IR, Raman, Dif-UV, TEM, and N 2 adsorption/desorption isotherms using Brunauer-Emmett-Teller (BET). Also, The first principle DFT calculations were performed to study the band structure and charge distribution of the spinel compounds, and the results showed the presence of a direct bandgap at the G symmetry point. The Optoelectronic properties revealed that the energy bandgap values of CoAl 2-x La x O 4 decreased from 3.7 to 2.8 eV upon increasing the La ratio. The photocatalytic activities were evaluated in the removal of the textile dye (RhB) from aqueous solutions. Several conditions such as initial dye concentrations and contact times were investigated. The mechanism of photocatalytic activity of CoAl 2-x La x O 4 (x =0.00 and 0.07) substitution on the RhB above the liquid surface make clear that both hydroxyl and superoxide anions radicals are the main active species that play the main role in removing RhB from solutions. The PL spectra were measured to suggest the impact of La dopant on the photoactivity of the CoAl 2 O 4 . The blue shift in the visible emission peak was caused by the quantum size effect in cobalt aluminate nanostructures due to the substitution of Al 3+ with La 3+ ions. Also, PL intensity decreased dramatically when the La 3+ substitution with the Al 3+ ions.
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