光催化
材料科学
太阳能转换
太阳能
能量转换
纳米技术
化学工程
能量(信号处理)
建筑
环境科学
化学
物理
催化作用
工程类
电气工程
热力学
艺术
生物化学
视觉艺术
量子力学
作者
Peipei Li,Naheed Hossain,Peikui Wang,Andréas Ruediger,Jérôme P. Claverie
出处
期刊:ACS applied nano materials
[American Chemical Society]
日期:2024-04-06
标识
DOI:10.1021/acsanm.4c00409
摘要
Significant progress has been achieved in elucidating the relationship between the architecture of heterogeneous photocatalysts and their catalytic activity. Notably, it is recognized that hollow nanospheres exhibit superior catalytic activity compared with their filled nanoparticle counterparts. Yet, the impact of diameter and shell thickness on photocatalytic activity remains unclear. Here, we designed hollow TiO2 nanospheres with varying thicknesses and diameters. Our study reveals that disparities in catalytic activity, for processes such as H2 production, N2 reduction, or dye degradation, defy simple attribution to defects, surface facets, surface area, or variations in exciton lifetimes. Intriguingly, a decrease in catalytic activity was observed with an increase in the external diameter or shell thickness. The absorption and scattering of a single hollow nanosphere increase with particle diameter and shell thickness. However, at a given concentration, nanospheres with lower shell thickness and external diameter are in greater numbers, thus resulting in overall greater absorption and scattering for hollow nanospheres with lower diameter and diameter. We envision that this study will provide a foundation for the rational design of nanomaterials with enhanced photoactivity.
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