Construction of Axially Chiral Biaryl Sulfonamides by Palladium/Chiral Norbornene Cooperative Catalysis

We herein report a highly efficient method for the enantioselective synthesis of axially chiral biaryl sulfonamides via palladium/chiral norbornene cooperative catalysis, exploiting readily available aryl iodides, bulky 2‐bromobenzenesulfonamides and olefins as the reactants. This approach demonstrates broad substrate scope, excellent enantioselectivities, step economy, and scalability.