化学
卡宾
叶立德
重氮
艾伦
铜
催化作用
共轭体系
反应性(心理学)
环丙烷化
组合化学
药物化学
有机化学
替代医学
聚合物
病理
医学
作者
Hong Zhang,Jieyin He,Wendi Xu,Liangliang Yang,Xue Zhang,Haiyang Wang,Ming Lang,Jian Wang,Shiyong Peng
出处
期刊:Organic Letters
[American Chemical Society]
日期:2022-09-26
卷期号:24 (39): 7095-7100
被引量:4
标识
DOI:10.1021/acs.orglett.2c02620
摘要
An unprecedented copper-catalyzed cascade reaction of 1,6-enynes with sulfoxonium ylides is reported, providing a series of structurally intriguing 2,3-disubstituted indolines bearing a conjugated dienone functionality at the 3-position in moderate to excellent yields with good chemo-, regio-, and diastereoselectivities under mild reaction conditions. Importantly, sulfoxonium-ylide-derived copper-carbene herein exhibits quite different reactivity from that of diazo copper-carbene. A rational mechanism, an initial ammonium ylide rather than allene formation, is proposed.
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