乙醇醛
甲酰化
化学
催化作用
块(置换群论)
电合成
有机化学
组合化学
光化学
电化学
物理化学
几何学
电极
数学
作者
Matthew T. Flynn,Xin Liu,Andrea Dell'Acqua,Jabor Rabeah,Angelika Brückner,Eszter Baráth,Sergey Tin,Johannes G. de Vries
出处
期刊:Chemsuschem
[Wiley]
日期:2022-09-08
卷期号:15 (20)
被引量:4
标识
DOI:10.1002/cssc.202201264
摘要
Biomass derived glycolaldehyde was employed as C1 building block for the N-formylation of secondary amines using air as oxidant. The reaction is atom economic, highly selective and proceeds under catalyst free conditions. This strategy can be used for the synthesis of cyclic and acyclic formylamines, including DMF. Mechanistic studies suggest a radical oxidation pathway.
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