阳极
阴极
材料科学
超级电容器
电化学
磷化物
功率密度
石墨烯
化学工程
电极
纳米技术
化学
镍
冶金
功率(物理)
物理
物理化学
量子力学
工程类
作者
Haoyan Meng,Shilong Wang,Xueying Ma,Dehao Zhang,Linlin Zhang,Xuying Liu,Li Zhang
出处
期刊:Small
[Wiley]
日期:2023-02-12
卷期号:19 (18)
被引量:12
标识
DOI:10.1002/smll.202207496
摘要
It is extremely crucial to design and match high-quality cathode and anode for achieving high-performance asymmetric supercapacitors (ASCs). Herein, Co3 (PO4 )2 @NiCo-LDH/Ni foam (CP@NCOH/NF) cathode with hierarchical morphology and graphene hydrogel/Fe-Ni phosphide/Ni foam (GH/FNP/NF) anode with the robust and porous structure are elaborately designed and prepared, respectively. Owing to their unique and profitable structures, both CP@NCOH/NF and GH/FNP/NF electrodes yield the superior capacity (10760 and 2236 mC cm-2 at 2 mA cm-2 , respectively), good rate capability (63% retention at 200 mA cm-2 and 52% retention at 50 mA cm-2 , respectively), and excellent cycling stability (72% and 74% retention after 10 000 cycles, respectively). Benefiting from their matchable electrochemical performances, the configured solid-state CP@NCOH/NF//GH/FNP/NF ASC outputs both competitive energy density (80.2 Wh kg-1 /4.1 mWh cm-3 ) and power density (14563 W kg-1 /750 mW cm-3 ), companied by remarkable cyclability (71% retention after 10 000 cycles), manifesting its great promise for large-scale integrated energy-storage system.
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