假电容器
电解质
超级电容器
材料科学
复合数
电极
化学工程
储能
电流密度
电容
钙钛矿(结构)
导电体
功率密度
复合材料
化学
物理化学
量子力学
物理
工程类
功率(物理)
作者
Priyanshu Goel,Akash Deep,Sunita Mishra
标识
DOI:10.1016/j.jallcom.2022.167991
摘要
Perovskite phase metal oxides are extensively explored due to their structural and compositional flexibility and excellent electrocatalytic activity. Its composite with the porous and conductive materials has potential application for the energy storage devices due to its additional conductive pathways for enhancing the charge kinetics. In the present work synthesis of highly porous Cu-MOF(HKUST-1)/LaNiO3 heterostructure composite is explored as pseudocapacitive electrode in three electrode system using KOH as well as LiOH electrolytes. The prepared HKUST-1/LaNiO3 composite electrode has shown a high specific capacitance of 424.30 F/g, 786.0 F/g in LiOH and KOH electrolytes respectively at 1 A/g current density. The obtained value is significantly better than the pristine LaNiO3 perovskite electrode (170 F/g and 273 F/g in LiOH and KOH respectively). The symmetrical supercapacitor using HKUST-1/LaNiO3 electrodes have displayed the energy densities of 28.24 Wh/kg and 28.15 Wh/kg and power densities of 775 W/kg, 836 W/kg in KOH and LiOH electrolytes respectively.
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