糠醛
加氢脱氧
催化作用
产量(工程)
化学
甲醇
羟醛缩合
生物量(生态学)
有机化学
羟醛反应
材料科学
选择性
海洋学
冶金
地质学
作者
Kuilin Yuan,Wen Zhang,Yaohong Zhou,Xiaohua Zhang,Shangxing Chen,Jing Chen,Changxiang Liu,Wan-Ming Xiong
出处
期刊:ACS Sustainable Chemistry & Engineering
[American Chemical Society]
日期:2023-12-07
卷期号:11 (50): 17769-17777
被引量:1
标识
DOI:10.1021/acssuschemeng.3c05865
摘要
A novel strategy for preparing 1,13-tridecanediol by valorization of furfural was proposed, involving aldol condensation to build C13 intermediates and further hydrodeoxygenation. During this process, Raney Ni exhibited excellent catalytic performance for the initial hydrogenation (C═C and C═O) with a yield of 98.30%, while Pd/TiO2–ZrO2 showed promising de–OH and ring opening performance. Results showed that ZrO2 was necessary for de–OH and ring opening, and the catalytic performance could be improved by incorporating with TiO2 to form TiO2–ZrO2 due to the increase in weak acid sites. Also, the introduction of Pd could further promote the reaction oriented toward obtaining 1,13-tridecanediol. After optimization, 1,13-tridecanediol yield could be straightforwardly up to 57.93% in water, and it would improve to 76.51% (69.64% based on furfural) by introducing trace amounts of methanol, and even the reaction parameters (time, pressure, temperature, etc.) contributed to the distribution of products. Additionally, mechanistic investigation revealed that there were multiple simultaneous or sequential reaction steps in the hydrodeoxygenation reaction, and the superior catalytic performance of Pd/TiO2–ZrO2 for oriented upgrading of furfural into 1,13-tridecanediol could be attributed to the synergistic effect of TiO2–ZrO2 and Pd. Overall, this work may provide some insights for the utilization of biomass resources in the future.
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