断链
聚合物
键裂
星形聚合物
反应速率常数
线型聚合物
明星(博弈论)
材料科学
链条(单位)
高分子化学
化学
复合材料
动力学
物理
天体物理学
有机化学
聚合
催化作用
天文
量子力学
作者
Derek C. Church,Gregory I. Peterson,Andrew J. Boydston
出处
期刊:ACS Macro Letters
[American Chemical Society]
日期:2014-06-17
卷期号:3 (7): 648-651
被引量:98
摘要
The effect of star versus linear polymer architecture on the rates of mechanochemically induced bond scission has been explored. We determined rate constants for chain scission of parent linear and star polymers, from which daughter fragments were cleanly resolved. These studies confirm a mechanistic interpretation of star polymer chain scission that is governed by the spanning rather than total molecular weight. We further demonstrate the preserved rate of site-selective mechanophore activation across two different polymer structures. Specifically, we observed consistent activation rate constants from three-arm star and linear polymer analogues, despite the Mn of the star polymer being 1.5 times greater than that of the linear system.
科研通智能强力驱动
Strongly Powered by AbleSci AI