One-Pot Synthesis of 6-(Pyridyl)salicylates by Formal [3+3] Cyclizations of 1,3-Bis(silyl enol ethers) with 3-Pyridyl-3-silyloxy-2-en-1-ones
作者
Peter Langer,Mirza Arfan Yawer,Abdolmajid Riahi,Muhammad Adeel,Ibrar Hussain,Christine Fischer
出处
期刊:Synthesis [Thieme Medical Publishers (Germany)] 日期:2008-04-01卷期号:2008 (8): 1276-1282被引量:1
标识
DOI:10.1055/s-2008-1042949
摘要
6-(Pyridyl)salicylates were regioselectively prepared by formal [3+3] cyclization of 1,3-bis(silyl enol ethers) with 3-(pyridyl)-3-silyloxy-2-en-1-ones. These reactions represent what are, to the best of our knowledge, the first [3+3] cyclizations of 1,3-bis(silyl enol ethers) with heterocyclic substrates.