纳米棒
材料科学
光电流
热液循环
单斜晶系
化学工程
正交晶系
退火(玻璃)
分解水
光催化
高分辨率透射电子显微镜
六角相
基质(水族馆)
纳米技术
相(物质)
晶体结构
光电子学
透射电子显微镜
催化作用
化学
结晶学
有机化学
复合材料
工程类
地质学
海洋学
作者
Shankara S. Kalanur,Yun Jeong Hwang,Sang Youn Chae,Oh‐Shim Joo
出处
期刊:Journal of materials chemistry. A, Materials for energy and sustainability
[The Royal Society of Chemistry]
日期:2013-01-01
卷期号:1 (10): 3479-3479
被引量:274
摘要
We demonstrate a facile hydrothermal method to grow oriented WO3 nanorods on a transparent conductive substrate without the assistance of any seed layer or structure directing agent for photocatalytic applications. The effects of hydrothermal growth conditions such as reaction time, precursor solution, and post annealing temperature on the crystalline phase and morphology of the WO3 on the FTO substrate are discussed. XRD studies reveal that the as-prepared orthorhombic WO3·0.33H2O nanorods are transformed to the hexagonal phase by post annealing at 400 °C. Moreover, post annealing above 500 °C converts them to monoclinic WO3 nanorods on the FTO substrate, which is the photoactive crystal phase of WO3 for water oxidation. The synthesized WO3 nanorods were revealed to have a single crystalline structure by HRTEM analysis. The photoelectrochemical water splitting properties of the annealed WO3 nanorod arrays were investigated in 0.5 M Na2SO4 under AM 1.5G illumination. The optimized WO3 nanorod arrays exhibit a photocurrent of 2.26 mA cm−2 at 1.23 V (versus RHE), and an incident photon-to-current conversion efficiency (IPCE) of as high as 35% at 400 nm for the photoelectrochemical oxidation of water. This simple hydrothermal method can allow the use of WO3 for photoanodic applications with high efficiency.
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