In recent years, more and more attentions have been paid to the research of producing solar grade silicon by the metallurgical methodboron removal has always been difficult and important in various technologies. In this paper the recent research on removing boron is summarized. The boron removal is calssfied by the different forms of boron in removing boron: gaseous-boron removal, solid-boron removal and electrorefining-boron removal. The principle and outcomes of each boron removal craft are survered and compared, the possible application prospect is predicted.