化学
稀释
香兰素
愈创木酚
泰勒分散
扩散
糠醛
分析化学(期刊)
热力学
呋喃
色谱法
有机化学
物理
催化作用
作者
Kazuko Yui,N. Yamazaki,Toshitaka Funazukuri
摘要
Infinite dilution binary diffusion coefficients (D12) for compounds derived from biomass such as furan-2-carbaldehyde (furfural), 5-(hydroxymethyl)-2-furaldehyde (5-HMF), 2-methoxyphenol (guaiacol), 4-hydroxy-3-methoxybenzaldehyde (vanillin), and phenol in water were measured over the temperature range from (298.2 to 353.2) K at 0.1 MPa using the Taylor dispersion method. The relative expanded uncertainties with level of confidence 0.95 (the coverage factor, k = 2.78 for 4 degrees of freedom) for the measured diffusion coefficients were less than 5.8 % and typically ca. 2.4 %. The diffusion coefficients were correlated with the hydrodynamic equation, D12/T = αηβ, with an average absolute relative deviation, AARD, less than 1.16 %.
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