Trifluoromethylation and Monofluoroalkenylation of Alkenes through Radical–Radical Cross‐Coupling

Abstract The first visible‐light‐induced trifluoromethylation and monofluoroalkenylation of simple alkenes via a challenging radical–radical cross‐coupling step was achieved. This method provided a mild, step‐economical and redox‐neutral route to privileged two different fluorinated difunctionalized allyl compounds. The utility of this method is illustrated by late‐stage modification of medically important molecules.