甲脒
三碘化物
碘化物
铯
材料科学
能量转换效率
钙钛矿(结构)
退火(玻璃)
热稳定性
溴
相(物质)
兴奋剂
带隙
光电子学
化学
无机化学
有机化学
物理化学
结晶学
冶金
复合材料
电解质
色素敏化染料
电极
作者
Hanul Min,Maengsuk Kim,Seungun Lee,Hyeonwoo Kim,Gwisu Kim,Keunsu Choi,Jun Hee Lee,Sang Il Seok
出处
期刊:Science
[American Association for the Advancement of Science (AAAS)]
日期:2019-11-08
卷期号:366 (6466): 749-753
被引量:939
标识
DOI:10.1126/science.aay7044
摘要
Maintaining the bandgap The bandgap of the black α-phase of formamidinium-based lead triiodide (FAPbI 3 ) is near optimal for creating high-efficiency perovskite solar cells. However, this phase is unstable, and the additives normally used to stabilize this phase at ambient temperature—such as methylammonium, caesium, and bromine—widen its bandgap. Min et al. show that doping of the α-FAPbI 3 phase with methylenediammonium dichloride enabled power conversion efficiencies of 23.7%, which were maintained after 600 hours of operation. Unencapsulated devices had high thermal stability and retained >90% efficiency even after annealing for 20 hours at 150°C in air. Science , this issue p. 749
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