One-Step Fabrication of a Micro/Nanosphere-Coordinated Dual Stimulus-Responsive Nanofibrous Membrane for Intelligent Antifouling and Ultrahigh Permeability of Viscous Water-in-Oil Emulsions

Membrane fouling is a major challenge for long-term oil/water separation. The incomplete degradation of organic pollutants or membrane damage exists in the common methods of membrane regeneration. Herein, a dual-responsive nanofibrous membrane with high water-in-oil emulsion separation efficiency and smart cleaning properties is reported, which shows complete restoration of its original separation performance. The pH-responsive and upper critical solution temperature (UCST)-type thermoresponsive nanofibrous membrane with a micro/nanosphere structure was developed via a one-step-blending electrospinning strategy. The membrane displays high hydrophobicity/oleophilicity at pH 7 and 25 °C and hydrophilicity/oleophobicity at pH 3 and 55 °C. As a result, it exhibits an ultrahigh permeability of 60528.76 L m–2 h–1 bar–1 and a separation efficiency of 99.5% for water-in-D5 emulsions at room temperature (25 °C). Moreover, the contaminated membranes could be easily reclaimed by being rinsed with warm acidic water (pH 3 and 55 °C). The membrane maintained high separation performance after being used for multiple cycles, indicating its scalable application for purifying emulsified oil. This study provides a facial method of constructing membranes with multiscale hierarchical structures and a new idea for the design of recyclable oil/water separation membranes.