化学
试剂
催化作用
组合化学
有机合成
有机化学
作者
G. Santosh,Samata E. Shetgaonkar,Fateh V. Singh
标识
DOI:10.2174/1570179419666220211102602
摘要
Organoselenium chemistry has developed as an important tool in the field of synthetic and medicinal chemistry. Various organoselenium reagents have been developed and used successfully to achieve different organic transformations such as selenocyclizations, oxyselenenylations, selenoxide eliminations, etc. Additionally, organoselenium reagents' potential is not limited to their use as stoichiometric reagents, but they have been successfully used as organocatalysts in a number of synthetic transformations. Various organic and inorganic oxidants have been identified as terminal oxidants to regenerate the active catalytic species. In this review article, the recent progress of organoselenium reagents in catalysis is being highlighted along with their asymmetric variants.
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