Heterogenization of Molecular Electrocatalytic Active Sites through Reticular Chemistry

The electrochemical conversion of small molecules, such as CO₂ , O₂ , and H₂ O, has received significant attention as a potential engine for sustainable life. Metal-organic frameworks (MOFs) are a promising class of electrocatalytic materials for such processes. An attractive aspect of utilizing this class of materials as electrocatalysts is that well-known molecular active sites can be introduced to well-defined crystalline heterogeneous catalytic systems with high tunability. This review offers strategic insights into recent studies on MOF-based electrocatalysts by discussing the notable active sites that have been utilized in both homogeneous and heterogeneous catalysts, while highlighting instances where such active sites have been introduced into MOFs. In addition, material design principles enabling the integration of electrochemically active components with the MOF platform are outlined. Viewpoints on the viability of MOFs as an alternative to currently used electrocatalysts are also discussed. Finally, the future direction of MOF-based electrocatalysis research is established.