枝晶(数学)
锌
阳极
水溶液
材料科学
金属
电镀(地质)
分子
电解质
溶剂化
剥离(纤维)
无机化学
结晶学
化学工程
化学
冶金
物理化学
有机化学
电极
复合材料
工程类
地质学
数学
地球物理学
几何学
作者
Meijia Qiu,Peng Sun,Aimiao Qin,Guofeng Cui,Wenjie Mai
标识
DOI:10.1016/j.ensm.2022.04.018
摘要
The long-term reversible plating/stripping of Zn anodes is one of the decisive parts inside various Zn based aqueous batteries, but originally restricted by irregular dendrite/by-products issues. Guided by the metal-coordination chemistry, a novel additive, sorbitol (SBT), is introduced into the traditional ZnSO4 electrolyte to achieve preferred (002) orientation growth with stably invertible Zn deposition, while modulate the primary solvation structure for Zn2+ through expelling some active H2O molecules to alleviate common side reactions, simultanously. The robust Zn2+-SBT compound enables a much weaker interaction with (002) than (100) and (101), inducing its slower growth and resulting in its ultimate exposure. With a lower surface energy, the primary (002) on Zn anode surface effectively impedes the occurrence of Zn dendrite and several by-products. Excellent stabilities have finally been realized in Zn-Zn symmetric cells and several kinds of full cells, elucidating its potential in future Zn based aqueous devices.
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