Photocatalytic activity of self-heterojunctioned intermediate phases in HCl protonated and HNO3 deconjugated g-C3N4 nanostructures

This research involved the different acid-treatment conditions of graphitic carbon nitride and its modified nanostructures through thermal polycondensation of urea at various temperatures. X-ray diffraction patterns revealed that processing at a lower temperature than 500 °C resulted in melem and its derivatives, indicating incomplete transformation of urea to g-C₃N₄. However, treatment at higher temperatures and the HCl acid treatment led to the formation and expansion of g-C₃N₄ networks, as evidenced by notable differences in peak intensities observed in their Fourier-transform infrared and Raman spectra. Scanning electron microscopy analysis illustrated a transition from the granular morphology of melamine to the layered structure characteristic of g-C₃N₄. The nanoparticle morphology observed in the HNO₃ acid treatment sample was attributed to the deconjugation of nanosheets through the highly oxidative acid medium. The most suitable photocatalytic activity for Methylene Blue (MB) degradation under UV and visible light illumination was observed for the samples prepared at 550 °C and HCl post-processed nanostructures. It is proposed that the enhanced photocatalytic activity observed in these samples is most likely attributed to the reduced recombination of photogenerated charge carriers facilitated by heterojunctions formed between different intermediate phases. These findings highlight the potential of modified g-C₃N₄ and its derivatives as promising photocatalytic materials for water purification applications.