Rational Design and Facile Preparation of Palladium‐Based Electrocatalysts for Small Molecules Oxidation

Direct liquid fuel cells (DLFCs) can convert the chemical energy of small organic molecules directly into electrical energy, which is a promising technique and always calls for electrocatalysts with high activity, stability and selectivity. Palladium (Pd)-based catalysts for DLFCs have been widely studied with the pursuit of ultra-high performance, however, most of the preparation routes require complex agents, multi-operation steps, even extreme experimental conditions, which are high-cost, energy-consuming, and not conducive to the scalable and sustainable production of catalysts. In this review, the recent progresses on not only the rational design strategies, but also the facile preparation methods of Pd-based electrocatalysts for small molecules oxidation reaction (SMOR) are comprehensively summarized. Based on the principles of green chemistry in material synthesis, the basic rules of "facile method" have been restricted, and the fabrication processes, perks and drawbacks, as well as practical applications of the "real" facile methods have been highlighted. The landscape of this review is to facilitate the mild preparation of efficient Pd-based electrocatalysts for SMOR, that is, to achieve a balance between "facile preparation" and "outstanding performance", thereby to stimulate the huge potential of sustainable nano-electrocatalysts in various research and industrial fields.