Pollution profiles, influencing factors, and source apportionment of target and suspect organophosphate esters in ambient air: A case study in a typical city of Northern China

Organophosphate esters (OPEs) are attracting attention because they pose risks to biota, including humans. Little research has been performed into the environmental fates of OPEs in the atmosphere. Here, target/suspect OPEs were determined in 122 atmosphere samples (gas phase (n = 31), PM2.5 (n = 30), PM10 (n = 30), and total suspended particles (n = 31)) from a city in Northern China. Pollution profiles were established, influencing factors identified, and sources apportioned. We found 12 target OPEs and 29 suspect OPEs. The target and suspect OPE concentrations in the ambient air samples were 2.2-172.5 and 0.7-53.9 ng/m3, respectively. Tris(chloroethyl) phosphate, tris(1-chloro-2-propyl) phosphate, and tris(2,4-di-t-butylphenyl) phosphate were the dominant OPEs in all samples. The OPEs were not in equilibrium, indicated by a multi-parameter linear free energy relationship model. The air quality index and OPE concentrations significantly correlated, indicating that OPE pollution is often more serious during weather with worse air quality. The target and suspect screening strategy and a positive matrix factorization model allowed OPE sources to be apportioned, improving our understanding of OPE sources. The four dominant sources were (1) construction, (2) indoor emissions, (3) the plastic industry and industrial activities, and (4) traffic emissions, textiles, and foam products.