光致发光
材料科学
异质结
比例(比率)
Crystal(编程语言)
纳米技术
光电子学
物理
量子力学
计算机科学
程序设计语言
作者
Xiaoyu He,Yaxin Wu,Shenghong Liu,Wei He,Shaohua Li,Guoyan Huo,Longtao Jiang,Yu. V. Kapitonov,Guichuan Xing,Yinghe Zhao,Yuan Li,Tianyou Zhai
标识
DOI:10.1002/adfm.202403273
摘要
Abstract In contrast to conventional atomic crystals, two‐dimensional inorganic molecular crystals (2DIMCs) possess a unique crystal structure composed of small molecules held together by van der Waals force. Such distinctive structure grants them specific chemical and physical properties highly suitable for electronic and optoelectronic applications. However, the synthesis of 2DIMCs has posed significant challenges due to the inherent issues such as uncontrollable growth orientation stemming from their natural crystalline isotropy and poor stability resulting from the weak intermolecular connections. Addressing these obstacles, the preparation of large‐scale and highly‐stable 2DIMC BiBr 3, and its heterostructure are reported here by developing crystallization orientation engineering strategies. This approach has successfully yielded centimeter‐scale 2DIMC BiBr 3 with a clean and dense surface, showcasing exceptional long‐term air‐stability exceeding 80 days. Furthermore, the universal growth of large‐scale 2DIMC BiBr 3 is demonstrated on diverse substrates, including SiO 2 , Al 2 O 3 , and MoS 2 monolayers. Notably, the resultant 2D BiBr 3 /MoS 2 heterostructure exhibits remarkable photoluminescence enhancement. This contribution paves a universal avenue for the mature synthesis of large‐scale 2DIMCs with superior stability, holding great promise for prompting their integration in practical electronic and optoelectronic devices.
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