Electrically Driven Biocatalysis for Sustainable CO2‐to‐Chemicals Transformation

The catalytic transformation of CO 2 into value‐added chemicals has become a critical strategy for mitigating environmental issues and generating economic benefits. Although substantial progress has been made in renewable electricity‐driven CO 2 conversion into C 1 / C 2 products, the efficient synthesis of high‐value, and long‐chain compounds remains a significant challenge. Biosynthesis offers a feasible route for producing long‐chain value‐added products at mild conditions. Consequently, the integration of electrocatalysis with bioconversion has emerged as a promising approach for sustainable CO 2 conversion. This short review outlines recent advances in the sustainable synthesis of long‐chain compounds from CO 2 via electrically driven biocatalysis, highlighting innovative coupling strategies that combine electrochemical and biochemical processes. Furthermore, the remaining challenges and prospects are tentatively discussed for further advancing CO 2 ‐based sustainable synthesis.