镍
电化学
合金
串联
硝酸盐
氨
材料科学
封面(代数)
冶金
还原(数学)
无机化学
化学
复合材料
电极
有机化学
工程类
机械工程
几何学
物理化学
数学
作者
Kartick Chandra Majhi,Hongjiang Chen,Asma Batool,Qi Zhu,Yangxin Jin,Shengqin Liu,Patrick H.‐L. Sit,Jason Chun‐Ho Lam
标识
DOI:10.1002/anie.202505571
摘要
Nitrate electrocatalytic reduction to ammonia occurs with exceptional performance on ultrathin-sheet-assembled Fe80Ni20 nanoflowers, as described by Jason Lam et al. in their Research Article (e202500167). Mechanistic studies revealed that NO3 preferentially adsorbs and is reduced to NO2 on the Fe surface. Subsequently, NO2 is efficiently hydrogenated to NH3 on the Ni surface. This in-tandem mechanism between Fe and Ni significantly enhances the electrocatalytic reduction of NO3 to NH3.
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