光催化
催化作用
复合数
碳化
吸附
化学工程
硫化物
选择性
材料科学
生物炭
呋喃
硫化镉
糠醛
水热碳化
壳聚糖
化学
核化学
无机化学
热解
有机化学
复合材料
工程类
作者
Chuan Yuan,Qian Liu,Manman Wei,Shuang Zhao,Xuping Yang,Bin Cao,Shuang Wang,Abd El-Fatah Abomohra,Xinlin Liu,Yamin Hu
出处
期刊:Fuel
[Elsevier]
日期:2022-07-01
卷期号:320: 123994-123994
被引量:7
标识
DOI:10.1016/j.fuel.2022.123994
摘要
In the present study, a self-doped N-doped chitosan carbon (Ch) was prepared by activated carbonization as a carrier. A series of CdS QDs/xCh composite photocatalysts were synthesized by hydrothermal method to support CdS QDs with different contents. Catalytic oxidation of 5-hydroxymethyl furfural (HMF) was performed to produce 2,5-diformyl furan (DFF). Results showed that 20% Ch loading (CC-20), 10 h reaction time, and 1/4 raw material/catalyst ratio, HMF conversion rate of 78.73% and DFF selectivity of 97.31% were achieved. Through 5 cycles of experiments on CC-20, results showed less than 10% reduction in photocatalytic degradation rate of CC-20 composite photocatalyst, which confirms good stability and cyclability of the catalyst. Finally, through a series of characterization, the structure, composition, morphology, and photoresponse properties of the composite photocatalyst were investigated; at the same time, the mechanism and conversion path of CdS QDs/Ch photocatalyst were explored.
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