A UV‐Reflective Organic–Inorganic Tandem Structure for Efficient and Durable Daytime Radiative Cooling in Harsh Climates

Radiative cooling shows great promise in eco-friendly space cooling due to its zero-energy consumption. For subambient cooling in hot humid subtropical/tropical climates, achieving ultrahigh solar reflectance (≥96%), durable ultraviolet (UV) resistance, and surface superhydrophobicity simultaneously is critical, which, however, is challenging for most state-of-the-art scalable polymer-based coolers. Here an organic-inorganic tandem structure is reported to address this challenge, which comprises a bottom high-refractive-index polyethersulfone (PES) cooling layer with bimodal honeycomb pores, an alumina (Al₂ O₃ ) nanoparticle UV reflecting layer with superhydrophobicity, and a middle UV absorption layer of titanium dioxide (TiO₂ ) nanoparticles, thus providing thorough protection from UV and self-cleaning capability together with outstanding cooling performance. The PES-TiO₂ -Al₂ O₃ cooler demonstrates a record-high solar reflectance of over 0.97 and high mid-infrared emissivity of 0.92, which can maintain their optical properties intact even after equivalent 280-day UV exposure despite the UV-sensitivity of PES. This cooler achieves a subambient cooling temperature up to 3 °C at summer noontime and 5 °C at autumn noontime without solar shading or convection cover in a subtropical coastal city, Hong Kong. This tandem structure can be extended to other polymer-based designs, offering a UV-resist but reliable radiative cooling solution in hot humid climates.