Surface Tension-Induced Eccentric Hollow Polysiloxane Microspheres in a Surfactant-Free System and Their Applications as a Nanoreactor and Nanomotor

Eccentric hollow polysiloxane microspheres (EHPMs) have attracted significant attention due to their potential in energy storage, drug delivery, and heterogeneous catalysis applications. However, their preparation pathways are often particularly complex. Therefore, it is critical to find a simple method for preparing EHPMs. In this study, a surfactant-free emulsification method is proposed to prepare EHPM. Under acidic conditions, methyl triethoxysilane (MTES) is hydrolyzed at the oil-water interface, with the hydrolyzed MTES demonstrating amphiphilic properties, and it could be anchored on the xylene surface to form an oil-in-water emulsion. The solution, when adjusted to alkaline, nucleated from a point at the oil-water interface. Driven by the surface tension, the hydrolyzed MTES migrated to the nucleation site with decreasing hydrophilicity. As a result, an EHPM formed. This process provides a simple, low cost, and environmentally friendly strategy for the preparation of EHPM, which demonstrated potential in catalytic and nanomotor applications.