NNaTaO3@Ta3N5 Core‐Shell Heterojunction with Controlled Interface Boosts Photocatalytic Overall Water Splitting

Abstract Ta 3 N 5 is a promising material for photocatalytic hydrogen production from water because of its suitable band structure for both solar energy collection and overall water splitting, while its application is restricted by severe charge recombination as well as non‐equilibrium redox capabilities. Herein, atomic‐scale N‐doped NaTaO 3 @Ta 3 N 5 (NNaTaO 3 @Ta 3 N 5 ) core‐shell cubes prepared by nitridation of cubic NaTaO 3 are reported. The core‐shell heterojunction cubes present efficient and stoichiometric evolution of H 2 and O 2 from photocatalytic overall water splitting, with a quantum efficiency of 2.18% at 550 nm without any cocatalyst. The success relies on the Ta 3 N 5 shell having a thickness of only ≈5 nm which enables increased lifetimes of the photogenerated charges. Moreover, the core‐shell heterojunction shows a type‐I band alignment that can steer smooth charge flow from NNaTaO 3 to Ta 3 N 5 , particularly with the assistance of the shared communal Ta atoms at the interface. This efficiency can be further improved to 6.28% by in situ deposition of a Rh@Cr 2 O 3 core‐shell cocatalyst, which is among the highest reported values over Ta 3 N 5 ‐based photocatalyst. This study offers a promising pathway for the construction of well‐defined heterojunctions with manipulated charge transfer behavior for photocatalytic overall water splitting.