碳纳米纤维
材料科学
电化学
碳纤维
纳米纤维
电容器
化学工程
纳米技术
复合材料
碳纳米管
化学
电极
复合数
工程类
电压
电气工程
物理化学
作者
Dharmendra S. Sharma,A. Patel,Sanjay N. Bariya,Yash G. Kapdi,Saurabh S. Soni,Nidhi Patel,Sanjay H. Panjabi,Vaibhav K. Patel
出处
期刊:ACS applied electronic materials
[American Chemical Society]
日期:2024-05-08
标识
DOI:10.1021/acsaelm.4c00320
摘要
One-dimensional (1D) nanofibers stand out as a promising candidate for energy storage applications, particularly in the domain of supercapacitors. Their inherent advantages, including a high surface area, enhanced charge transport capabilities, and improved electrochemical performance, make them an intriguing focus of investigation. In this study, we present a thorough exploration of the synthesis, characterization, and application of PbS nanoparticles incorporated within the electrospun matrix of a polyacrylonitrile–polyaniline (PAN–PANI) blend. The subsequent carbonization process at 700 °C yields carbon nanofibers (CNFs) with tailored structural and electrochemical attributes. The resulting carbonized PbS/PAN–PANI nanofibers (NFs) exhibit exceptional electrochemical properties, including high specific capacitance, specific energy, and specific power, making them promising candidates for supercapacitor applications. Notably, the application of these CNFs in a two-electrode symmetrical supercapacitor device yielded a specific capacitance of 145.6 F g–1, as determined from galvanostatic charge–discharge (GCD) measurements at a current density of 0.5 A g–1 in a 6 M KOH electrolyte. Furthermore, this device demonstrated remarkable capacitive retention, maintaining 92.45% of its initial capacitance after 10 000 charge–discharge cycles at 1 A g–1. These outcomes not only affirm the robustness of the fabrication and optimization methodologies but also accentuate the potential of PbS/PAN–PANI CNFs as electrodes for high-performance supercapacitor systems, particularly highlighting their outstanding pseudocapacitive behavior and stability in alkaline electrolytes.
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