金属有机骨架
材料科学
聚合物
灵活性(工程)
金属
化学工程
溶剂
纳米技术
作者
Seonghwan Lee,Seok Jeong,Junmo Seong,Jaewoong Lim,Amitosh Sharma,Somi Won,Dohyun Moon,Seung Bin Baek,Myoung Soo Lah
出处
期刊:Materials Chemistry Frontiers
[The Royal Society of Chemistry]
日期:2021-05-04
卷期号:5 (9): 3621-3627
被引量:1
摘要
A new interdigitated two-dimensional (2D) layered metal–organic framework (MOF) with switchable framework flexibility is synthesized using a highly flexible multifunctional dicarboxylate ligand capable of π–π stacking and hydrogen bonding interactions. The framework flexibility and CO2 adsorption behavior of the 2D layered MOF can be controlled by guest N,N-dimethylacetamide (DMA) molecules encapsulated in the solvent pores. Partial removal of the DMA molecule results in partial contraction of the framework, and the interlayer interactions of this partially contracted framework allow reversible expansion and contraction of the framework under CO2 at 195 K. On the other hand, the flexibility of a fully contracted interdigitated 2D framework with no DMA molecules in the solvent pores is distinctly different from that of a partially contracted framework. The interlayer interactions in a fully contracted framework are significantly stronger than those in a partially contracted framework. Notably, this framework does not exhibit framework expansion under the same conditions.
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