丙烯酸酯
电解质
材料科学
锂(药物)
化学工程
准固态
阴极
聚合物
电化学
化学
电极
复合材料
色素敏化染料
物理化学
医学
工程类
内分泌学
单体
作者
Quan-yao Liu,Maoxiang Jing,Rui Li,Zhen-hao Huang,Weiyong Yuan,Bowei Ju,Xiangqian Shen
出处
期刊:ACS applied energy materials
[American Chemical Society]
日期:2021-10-29
卷期号:4 (11): 12989-12997
被引量:2
标识
DOI:10.1021/acsaem.1c02622
摘要
Solid polymer electrolyte is expected to be widely used in solid-state lithium batteries due to its good manufacturability and safety. But the low ion conductivity, poor interface combination, and narrow adaptability to different electrodes are hindering the development of solid-state batteries. In this work, a rigid-flexible poly(ether-acrylate) (PEA) solid electrolyte membrane with high room-temperature ion conductivity (1.5 × 10–4 S/cm), electrochemical stability window (∼4.8 V), and lithium ion migration number (0.81) was prepared using a cross-linking polymerization method. The cathode/electrolyte integrated structure was also created via directly coating electrolyte precursor on the cathode surface to improve the cathode/electrolyte interface combination and decrease the interface impedance, which obviously enhanced the rate performance of the battery. This electrolyte is suitable for LiFePO4, LiCoO2, NCM622 different-voltage cathodes and lithium metal, Si–C, and graphite anodes, showing good practicality and development prospects in solid-state lithium and lithium metal-free batteries due to its good adaptability.
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