N,N-Dimethylformamide solvent assisted hydrothermal pretreatment of Chlorella for coproduction of sugar, nitrogenous compounds and carbon dots

Microalgae are considered as a promising alternative to fossil fuels due to their ease of cultivation, short growth cycle and no occupation of cultivated land. In this study, N,N-Dimethylformamide (DMF) solvent was employed to assist hydrothermal pretreatment of Chlorella for coproduction of sugar, nitrogenous compounds and carbon dots (CDs). The effect of pretreatment conditions on the composition and pyrolysis bio-oil distribution of hydrothermal solid residues as well as CDs characteristic were investigated by varying the temperature (180-220 ℃) and reaction time (1-9 h). The results showed that pretreated residues had higher cellulose. And the yield of sugar and N-contained compounds reached 41.59% and 63.57% in the pyrolysis bio-oil of pretreated algae residues, respectively. Moreover, CDs obtained from hydrothermal solution fluoresced red under 365 nm excitation. The paper provides a new method for the complete utilization of microalgae.