纳米棒
材料科学
石墨烯
超级电容器
化学工程
成核
纳米技术
氧化物
纳米颗粒
纳米结构
多孔性
电极
电化学
复合材料
化学
冶金
有机化学
物理化学
工程类
作者
T. Kavinkumar,N. Naresh,Georgeena Mathew,B. Neppolian
标识
DOI:10.1016/j.jallcom.2021.162052
摘要
In this work, the incorporation of porous reduced graphene oxide (RGO) as support for nickel cobaltite and its strong influence on a structural directing agent is studied. It was found in experimental results that the RGO nanosheets, especially the porous carbon network would be favorable to serve as the nucleation sites for the growth of NiCo2O4 nanorods. Importantly, the epoxy groups present in the porous RGO attract an aggregated NiCo2O4 nanoparticle to form aggregated nanorod-like morphology through dangling bonds. The specific capacity of the NiCo2O4/RGO hybrid (606.6 C g-1 at 1 A g-1) is two times superior than that of NiCo2O4 (282.6 C g-1) and the high-rate performance for NiCo2O4/RGO hybrid is 3.5 times better than that of NiCo2O4. An asymmetric supercapacitor constructed with NiCo2O4/RGO (positive electrode) and activate carbon (negative electrode) delivered a maximum energy density of 49.6 W h kg-1 and long cycle life. In addition, a flexible transparent supercapacitor device assembled with the NiCo2O4/RGO hybrid electrode achieved a large areal capacity (5.27 mC cm-2 at 75.5% transparency), high energy density (1.17 mW h cm-2) and outstanding mechanical flexibility.
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