石墨烯
材料科学
锂(药物)
复合数
电化学
化学工程
粒径
石墨
纳米技术
化学
复合材料
电极
医学
物理化学
内分泌学
工程类
作者
Houbin Liu,Miao Cui,Yan Meng,Qin Xu,Xinhe Zhang,Zhiyuan Tang
标识
DOI:10.1016/j.electacta.2014.05.028
摘要
Few layers graphene nanosheets (GS) are obtained by the reduction of graphite oxide (GO) via Lithium aluminium tetrahydride (LiAlH4) and Phosphorus tribromide (PBr3) as the deoxidizer. The LiFePO4/GS composite is prepared using a solution phase method followed by a calcination process with only 2 h at 600 °C. The effect of the GS content in LiFePO4/GS on the morphology and electrochemical performance of LiFePO4 particles is extensively investigated. Results show that the optimized amount of GS in LiFePO4/GS is 5%. The primary particle size of LiFePO4/5%GS is 100∼150 nm which are wrapped and connected homogeneously and loosely by GS with ∼4 layers. The GS can restrict the growth of LiFePO4 particle and construct an effective conductive network LiFePO4/GS composite, which all can enhance the conductivity of LiFePO4 particle. The LiFePO4/5%GS composite delivers a capacity of 155.4 mAhg−1 at 0.2 C, which is much higher than pure LiFePO4 (125.3 mAhg−1). Even at high rate of 5 C, a specific capacity of 124.3 mAhg−1 is achievable, with no obvious capacity fading after 100 cycles.
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