草酸盐
化学
邻苯三酚
水溶液
滴定法
螯合作用
无机化学
比色法
比色分析
离子
核化学
色谱法
有机化学
作者
Koshiro Inoue,Shunichi Aikawa,Yasumasa Fukushima
出处
期刊:Luminescence
[Wiley]
日期:2017-10-18
卷期号:33 (2): 277-281
被引量:18
摘要
Abstract The pyrogallol red (PR)‐based Cu 2+ complex was proven to be an effective and selective colorimetric chemosensing ensemble for recognition of oxalate over other anions in a perfect aqueous solution. The addition of oxalate to the PR–Cu 2+ complex resulted in a colour change from purple to orange colour due to the regeneration of PR by the chelation of oxalate with Cu 2+ , while other anions did not induce any significant colour change. Moreover, it was revealed that no obvious interference was observed during the titrations with oxalate into each other anion. Therefore, the PR–Cu 2+ complex can be used as a simple and practical colorimetric chemosensor for detecting oxalate.
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