Control of nuclearity in heterometallic CuII–MnIIcomplexes derived from asymmetric Schiff bases: structures and magnetic properties

Among three asymmetric Schiff bases used for the synthesis of heterometallic Cu^II–Mn^IIcomplexes, the one with N₂O₂donor atoms yielded a tetranuclear and a trinuclear complex whereas two N₂O₃donor ligands produced solely dinuclear complexes. The results of magnetic measurements have been justified by DFT study.