羧化
催化作用
炔烃
过渡金属
基质(水族馆)
三键
化学
二氧化碳
铜
金属
终端(电信)
组合化学
有机化学
双键
计算机科学
地质学
海洋学
电信
作者
Chang Qiao,Yu Cao,Liang‐Nian He
出处
期刊:Mini-reviews in Organic Chemistry
[Bentham Science]
日期:2018-06-01
卷期号:15 (4): 283-290
被引量:16
标识
DOI:10.2174/1570193x15666180101150819
摘要
The coupling reaction of terminal alkynes and CO2 provides a promising way to synthesize propiolic acids. Among the existing catalytic systems, transition-metal copper and silver exhibit excellent catalytic efficiency under mild conditions probably being attributed to the activation of C-C triple bond of terminal alkynes. In this aspect, efficient strategies for activating both substrate and CO2 are often smart choices. This review summarizes the development trend of the Cu/Ag-catalyzed carboxylation reactions of terminal alkynes with CO2, and representative examples are also discussed in detail. Keywords: Carbon dioxide, carboxylation, terminal alkyne, propiolic acids, transition metal, catalysis.
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