材料科学
弹性体
聚合物
荧光
分散性
罗丹明B
阻带
聚合
复合材料
光电子学
纳米技术
化学工程
光学
高分子化学
谐振器
生物化学
光催化
物理
工程类
催化作用
化学
作者
Christian Schäfer,Markus Gallei,Jasmin T. Zahn,Johann Engelhardt,G. P. Hellmann,Matthias Rehahn
摘要
A new strategy to achieve easily scalable triple stimuli-responsive elastomeric opal films for applications as stretch-tunable photonic band gap materials is reported. Novel monodisperse highly functional core-interlayer-shell beads are obtained by semicontinuous emulsion polymerization featuring a temperature-sensitive fluorescent rhodamine dye either locally restricted in the core or the shell of prepared beads. After extrusion and compression molding, homogeneous elastomeric opal films with fascinating stretch-tunable and temperature-dependent fluorescent properties can be obtained. Applying strains of only a few percent lead to significant blue shift of the reflected colors making these films excellent candidates for applications as deformation sensors. Higher strains up to 90% lead to a tremendous Bragg reflection color change caused by transition from the (111) to the (200) lattice plane. The well-ordered opaline structure with its stop band at the emission frequency of the incorporated fluorescent dye shows remarkable angle-dependent fluorescence suppression. Herein described elastomeric opal films can be valuable in a wide range of applications such as rewritable 3D optical data storage, tunable laser action, and sensing materials.
科研通智能强力驱动
Strongly Powered by AbleSci AI