Constructing Schottky junctions via Pd nanosheets on DUT-67 surfaces to accelerate charge transfer

The separation, transfer and recombination of charge often affect the rate of photocatalytic reduction of CO2. Schottky junctions can promote the rapid separation of space charge. Therefore, in this paper, Pd nanosheets were grown on the surface of DUT-67 by a hydrothermal method, and a Schottky junction was constructed between DUT-67 and Pd. Under the action of the Schottky junction, the CO yield of 0.3-Pd/DUT-67 reached 12.15 μmol/g/h, which was 17 times higher than that of DUT-67. Efficient charge transfer was demonstrated in photochemical experiments. The large specific surface area and the increased light utilization rate also contributed to the increase in the CO2 reduction efficiency. In addition, the mechanism of Pd/DUT-67 photocatalytic reduction of CO2 was proposed.