溶解有机碳
化学
混合(物理)
腐殖质
分析化学(期刊)
追踪
荧光
吸收(声学)
有色溶解有机物
环境化学
生物系统
土壤科学
土壤水分
有机化学
环境科学
光学
浮游植物
营养物
物理
操作系统
生物
量子力学
计算机科学
标识
DOI:10.1016/j.watres.2014.04.018
摘要
Despite the wide use of absorption and fluorescence spectroscopy for tracking the sources of dissolved organic matter (DOM), there are limited studies on evaluating their source discrimination capabilities at variable solution chemistry (pH, NaCl, Ca2+, and DOM concentration). For this study, we compared the applicability of several well-known spectroscopic indices via end member mixing analysis based on two contrasting DOM sources (Suwannee River fulvic acid and an algal DOM). The absorption coefficients and the intensities of fluorescent components from parallel factor analysis (PARAFAC) showed linear relationships with increasing algal carbon fraction in the mixture of the two DOMs. In contrast, although they still behaved conservatively, spectral ratio indices such as spectral slopes, ratios of PARAFAC components, humification index, and fluorescence index changed in nonlinear patterns with the mixing ratios. The indices based on PARAFAC results exhibited strong discrimination capabilities, as indicated by high susceptibility to the changes in DOM sources relative to the analytical precision. While variable NaCl concentrations had limited effects, most fluorescence indices were considerably affected by other solution chemistry such as pH, Ca2+, and DOM level. Our study demonstrated that the applicability of the source discrimination indices should be critically examined especially in the environments with notable changes in the solution chemistry. The solution chemistry effects could be minimized by adjusting samples to a constant condition prior to the measurements or otherwise the effects should be fully taken into account in interpreting the field observations.
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