化学
溴化物
溴乙烯
产量(工程)
碘
有机化学
高分子化学
溴
冶金
材料科学
作者
Derek H. R. Barton,George Bashiardes,Jean‐Louis Fourrey
出处
期刊:Tetrahedron
[Elsevier]
日期:1988-01-01
卷期号:44 (1): 147-162
被引量:100
标识
DOI:10.1016/s0040-4020(01)85102-4
摘要
The oxidation of hydrazones by iodine in the presence of strong organic bases (guanidines) has been studied. Improved yields of vinyl iodides can be obtained by inverse addition using dry solvents and with a final heating period where appropriate. The reaction has been extended to various dihydrazones with interesting results. In complementary studies hydrazones have been oxidized by phenylselenenyl bromide in the presence of strong organic bases to give the corresponding phenyl vinyl selenides in good yield.
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