材料科学
原位
硅酸铝
化学工程
矿物学
硅酸盐玻璃
分析化学(期刊)
结晶
作者
Zifu Wang,Thomas F. Cooney,Shiv K. Sharma
标识
DOI:10.1016/0016-7037(95)00063-6
摘要
In situ high-temperature Raman spectra are presented below and above the glass transition temperature (Tg) of the 0.5Na2O·0.5Fe2O3·3SiO2 (Fe-albite, NFSO), 1.5Na20·0.5Fe2O3·3SiO2 (NFS2), K2O·0.5Fe2O3·3SiO2 (KFS), and reduced K2O·FeO·3SiO2 (KFS-R) compositions. For the oxidized sample, there is a close structural relationship between the glass and the super-cooled melt above Tg. With increasing temperature, no coordination changes of Fe3+ and no new anionic species are observed in the oxidized melts. In the spectrum of fully polymerized Fe-albite (FeAb) glass, the increase in linewidth of the low frequency Raman band at 452 cm−1 and shift in the position of the band to higher frequency at high temperature indicate an increase in the extent of disorder and decrease of average T-O-T angle, where T = Si, Fe3+ in tetrahedral coordination. In the depolymerized glasses, (NFSI ) and KFS, the increase in intensities of the Raman bands associated with Q3 species, containing three bridging oxygen atoms per T cation, result from either a change in relative cross sections of Raman modes or from a net increase in Q3 species with increasing temperature. On the basis of observed changes in the Raman spectra of the reduced sample (KFS-R), it is proposed that most of the Fe2+ ions act as network modifier. This suggestion is justified by the observation of the polarization character of the spectra and the appearance of new Raman bands.
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