化学
对映选择合成
共轭体系
催化作用
锰
不对称诱导
金属salen络合物
合理设计
组合化学
有机化学
纳米技术
聚合物
材料科学
作者
Hidetada Sasaki,Ryo Irie,Takayuki Hamada,Kenji Suzuki,Tsutomu Katsuki
出处
期刊:Tetrahedron
[Elsevier]
日期:1994-01-01
卷期号:50 (41): 11827-11838
被引量:184
标识
DOI:10.1016/s0040-4020(01)89298-x
摘要
On the basis of the newly proposed hypothesis on the mechanism of asymmetric induction, highly efficient (salen)manganese(III) complex (3) was constructed as a catalyst for asymmetric epoxidation. With this catalyst, the highest level of enantioselectivity was realized in the epoxidation of various conjugated cis-olefins.
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