苝
二亚胺
阴极
有机太阳能电池
图层(电子)
材料科学
热稳定性
工作职能
化学工程
化学
有机化学
聚合物
物理化学
分子
工程类
作者
Sabrina Aufar Salma,Rahmatia Fitri Binti Nasrun,Qurrotun Ayuni Khoirun Nisa,Dong Hwan Son,Joo Hyun Kim
标识
DOI:10.1016/j.dyepig.2023.111345
摘要
Small molecules based on PDI with amino N-oxide (PDIN-O), dimethyldipropylenetriamino, (PDIN-N) and ethyl tosylate (PDIN-OTs) as the cathode buffer layer (CBL) in inverted type OSCs are prepared in this study. The application of PDIN-O as CBL inverted-type devices becomes challenging due to PDIN-O being unstable under heat treatment and tending to degrade. To enhance the thermal stability in the inverted type of devices we introduce the side group dimethyldipropylenetriamino and tosylate. The PCE of the device based on PDIN-O, and PDIN-OTs were 12.5, 13.3, and 14.2%, respectively. This paper provides the ability to modulate CBL in non-fullerene organic solar cells by introducing a side group to tune the work function at the cathode interface. The PDIN-OTs is a promising material for the CBL in the inverted type of device and become the vanguard for the next exploration by changing the counterion or side group side.
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