化学
催化作用
煅烧
产量(工程)
沸石
连续流动
Diels-Alder反应
空间速度
有机化学
二烯
选择性
热力学
机械
物理
天然橡胶
作者
K. Masuda,Sandip G. Agalave,Wenlong Chen,Shun‐ya Onozawa,Shigeru Shimada,Kazuhiko Sato,Shū Kobayashi
标识
DOI:10.1002/ajoc.202200382
摘要
Abstract Diels–Alder reactions of unactivated dienes with various dienophiles were investigated under continuous‐flow conditions. H‐beta zeolite was found to be a suitable catalyst for this type of transformation, allowing a good productivity of 1.88 kg/dm 3 ⋅day space‐time yield and exhibiting excellent catalyst durability over >72 h of continuous operation. The catalyst was easily recyclable up to four times by simple calcination, without loss of activity.
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