材料科学
正硅酸乙酯
微观结构
复合材料
无定形固体
复合数
涂层
基质(水族馆)
等温过程
结晶
化学工程
化学气相沉积
热膨胀
纳米技术
有机化学
化学
工程类
地质学
物理
海洋学
热力学
作者
Jinfeng Yan,Xiumei Wu,Qidong Liu,Yunping Li,Sen Yu
标识
DOI:10.1016/j.ceramint.2023.12.117
摘要
Silicon oxycarbide (SiOC) coatings were prepared through isothermal chemical vapor co-deposition by using two precursors of hexamethyldisilane (HMDS) and tetraethyl orthosilicate (TEOS). The microstructure, composition and the protectiveness on C/C composite against oxidation of the coatings prepared at temperatures ranging from 1423 K to 1563 K and pressures ranging from 500 Pa to 1200 Pa were investigated, respectively. After oxidation, cracks and defects were formed in the coatings of all conditions due to the volume shrinkage of amorphous SiO2 crystallization and the mismatch of thermal expansion coefficient (CTE) between SiOC coatings and substrate. The most oxidation-resistant SiOC coating was obtained at 1563 K and 500 Pa, which exhibited the lowest weight loss rate of 4.87 % after 12 h of oxidation at 1673 K in air condition.
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